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Производство оборудования и технологии
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Development Potential Bio-Oil

The major drawback of biomass is that the energy density is an order of magnitude lower than that of crude oil (Table 4-17). When it is further considered that biomass for fuel is a difficult to handle solid (grain is an exception in that it almost flows like water), this implies that fuel biomass can never be shipped economically over long intercontinental distances.

Table 4-17

Energy Densities of Various Fuels

Fuel

Particle Density

Bulk Density

Energy Density

GJ/m3 bulk

kg/m3

kg/m3

product

Crude oil

855

35.8

Coal

1350

700

21

Natural gas (80 bar)

57

2.9

Biomass

450

230

3.7

Bio-oil

1200

20

Gasoline

760

35

Methanol

784

19

Therefore, when contemplating really large biomass production, the first conver­sion that has to take place is to convert the biomass into a transportable product. The best way to accomplish this is by flash pyrolysis, which is a fast pyrolysis at a high temperature of 450^-75 °С. In this way the solid biomass is converted into a transport­able liquid with an energy density of about 20GJ/m3 (see Table 4-17), which is similar to that of methanol. The pyrolysis plants can be located anywhere, because they can be economically built on a reasonably small scale. A stand-alone gasifier is only likely to be economic for world-scale plants, and hence they always depend on biomass from a variety of sources. The energy conversion of flash pyrolysis is now 75% but could well increase to 80% in the future. The bio-oil product is a transportable material that has as its only disadvantage that it is corrosive due to the presence of organic acids. A big advantage is that it can be gasified with oxygen in the same commercial gasifiers that can process heavy oil fractions. An added advantage of bio-oil is that it is easily homogenized. Holt and van der Burgt (1997) proposed such a concept of decentralized flash pyrolysis plants feeding a single large gasification installation. Research on details of actual implementation is continuing (Henrich, Dinjus, and Meier 2002).

Table 4-18 lists some of the most important properties of bio-oils. Additional data, in particular of some important organic compounds in bio-oil, is contained in Henrich, Dijus, and Meier (2002). In terms of its suitability for gasification in a standard oil gasifier, the most important aspects are the pH (material selection of the feed train) and the alkaline ash content. This latter may favor the use of a radiation screen instead of simple refractory lining.

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